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The system analysis of the air environment condition in an average statistical city on the basis of the long-term monitoring of dangerous and harmful emissions from industrial plants and the city infrastructure has been performed. The physical model of the calculation of secondary transformations has been developed using the Gibbs method of the energy minimization under the worst weather conditions, on which basis the detailed thermodynamic analysis of possibility of the chemical transformations of the air environment has been carried out while atmosphere monitoring in a city.

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